18649-43-9

Basic information

• Product Name: (4-methoxyphenyl)-lambda~2~-plumbanyl - acetic acid (1:3)
• CAS NO: 18649-43-9
• Molecular Formula: C₁₃H₁₆O₇Pb
• Molecular Weight: 494.4858
• Mol File: 18649-43-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (4-methoxyphenyl)-lambda~2~-plumbanyl - acetic acid (1:3)(CAS DataBase Reference)
• NIST Chemistry Reference: (4-methoxyphenyl)-lambda~2~-plumbanyl - acetic acid (1:3)(18649-43-9)
• EPA Substance Registry System: (4-methoxyphenyl)-lambda~2~-plumbanyl - acetic acid (1:3)(18649-43-9)

Safety Data

• Hazardous Substances Data: 18649-43-9(Hazardous Substances Data)

Usage

General Description

The chemical "(4-methoxyphenyl)-lambda~2~-plumbanyl - acetic acid (1:3)" is a coordination compound consisting of one molecule of 4-methoxyphenylplumbanyl and three molecules of acetic acid. The compound contains a central lead atom coordinated to the 4-methoxyphenyl group and three acetic acid molecules. It is used in various chemical and industrial applications, such as in the manufacturing of organic compounds and as a catalyst in chemical reactions. (4-methoxyphenyl)-lambda~2~-plumbanyl - acetic acid (1:3) has potential uses in the field of materials science and nanotechnology due to its unique coordination chemistry and potential for creating new functional materials. However, it is important to handle this compound with care, as lead compounds can be toxic and proper safety precautions should be taken when working with it.

Upstream product

• 546-67-8 lead(IV) tetraacetate 
• 100-66-3 methoxybenzene 
• 13257-51-7 mercury(II) trifluoroacetate 
• 70744-47-7 (p-methoxyphenyl)tri-n-butylstannane 
• 5720-07-0 4-methoxyphenylboronic acid 

Downstream Products

• 84736-57-2 3-(4-methoxy-phenyl)-heptan-4-one 
• 121-97-1 4-Methoxypropiophenone 
• 74610-83-6 diethyl 2-isopropyl-2-(p-methoxyphenyl)propanedioate 
• 74610-78-9 5,5-bis(p-methoxyphenyl)-2,2-dimethyl-1,3-dioxan-4,6-dione 
• 74610-76-7 5-ethyl-5-(p-methoxyphenyl)-2,2-dimethyl-1,3-dioxan-4,6-dione 
• 19347-08-1 acetic acid 1-methyl-2-oxo-2-phenyl-ethyl ester 
• 35572-38-4 2-(4-methoxyphenyl)-1-phenylpropan-1-one 
• 93-55-0 1-phenyl-propan-1-one 
• 86387-70-4 2-(p-methoxyphenyl)-1-phenylprop-2-en-1-one 
• 86387-73-7 2-benzoyl-2,5-bis(p-methoxyphenyl)-6-phenyl-3,4-dihydro-2H-pyran 
• 84736-52-7 (+/-)-(2R,4S)-4-tert-butyl-2-(4'-methoxyphenyl)cyclohexanone 
• 7476-41-7 2-methyl-1-oxo-1-phenylpropan-2-yl acetate 
• 611-70-1 phenyl isopropyl ketone 
• 163615-86-9 1-(4-methoxyphenyl)-4,6,8-trimethylazulene 

Relevant articles and documents

Enantioselective construction of sterically hindered tertiary α-aryl ketones: A catalytic asymmetric synthesis of isoflavanones

A method for the catalytic asymmetric α-arylation of ketones bearing very sterically hindered aryl rings has been developed. This reaction occurs under mild conditions, in short reaction times and has been applied to the first catalytic asymmetric synthesis of isoflavanones.

Reaction of Arylboronic Acids and their Derivatives with Lead Tetra-acetate. The Generation of Aryl-lead Triacetates, and meta- and para-Phenylenebis(lead triacetate), in situ for Electrophilic Arylation

Arylboronic acids and some of their derivatives have been found to undergo a rapid boron-lead exchange with lead tetra-acetate.In the presence of a catalytic amount of mercury(II) acetate, the reaction produces mainly the aryl-lead triacetate, and it has been developed as a convenient method for in situ generation of these useful electrophilic C-arylating reagents.The reaction allows the generation for the first time of meta- and para-phenylenebis(lead triacetate), compounds which behave as meta- and para-phenylene dication equivalents.