1338599-11-3Relevant academic research and scientific papers
Synthesis of rhodium(i) complexes bearing bidentate nh,nr-nhc/phosphine ligands
Naziruddin, Abbas Raja,Hepp, Alexander,Pape, Tania,Hahn, F. Ekkehardt
, p. 5859 - 5866 (2011)
The N-alkyphosphine-substituted benzimidazoles 5 (R = methylenedicyclohexylphosphine), 7 (R = ethylene-di(tBu)phosphine), and 8 (R = ethylenedicyclohexylphosphine) have been prepared. The benzimidazoles react with [RhCl(COE)2]2 in th
Hydrogen Activation by an Iridium(III) Complex Bearing a Bidentate Protic NH,NR-NHC^Phosphine Ligand
Cepa, Steffen,Schulte To Brinke, Christian,Roelfes, Florian,Hahn, F. Ekkehardt
, p. 5454 - 5460 (2015)
Benzimidazole 2 bearing an N1-(biscyclohexylphosphine)ethyl tether cleaves [IrCpCl2]2 to yield the mononuclear phosphine complex [3]. Heating of [3] yields via a formal C/N tautomerization complex [4]Cl with a protic NHC. Complex [4]
