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1338603-10-3

RuH(κ3N-1,3-di(2-pyridyl)-2-azaallyl)(PPh3)2 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1338603-10-3 Structure

  • Basic information

    1. Product Name: RuH(κ3N-1,3-di(2-pyridyl)-2-azaallyl)(PPh3)2
    2. Synonyms:
    3. CAS NO:1338603-10-3
    4. Molecular Formula:
    5. Molecular Weight: 822.891
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1338603-10-3.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: RuH(κ3N-1,3-di(2-pyridyl)-2-azaallyl)(PPh3)2(CAS DataBase Reference)
    10. NIST Chemistry Reference: RuH(κ3N-1,3-di(2-pyridyl)-2-azaallyl)(PPh3)2(1338603-10-3)
    11. EPA Substance Registry System: RuH(κ3N-1,3-di(2-pyridyl)-2-azaallyl)(PPh3)2(1338603-10-3)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1338603-10-3(Hazardous Substances Data)

1338603-10-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1338603-10-3 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,3,8,6,0 and 3 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1338603-10:
(9*1)+(8*3)+(7*3)+(6*8)+(5*6)+(4*0)+(3*3)+(2*1)+(1*0)=143
143 % 10 = 3
So 1338603-10-3 is a valid CAS Registry Number.

1338603-10-3Downstream Products

1338603-10-3Relevant articles and documents

From amine to ruthenaziridine to azaallyl: Unusual transformation of di-(2-pyridylmethyl)amine on ruthenium

Prokopchuk, Demyan E.,Lough, Alan J.,Morris, Robert H.

, p. 10603 - 10608 (2011)

The complexation of di-(2-pyridylmethyl)amine to RuHCl(PPh 3)3 affords the salt [RuH{κ3N-fac-1,3-di- (2-pyridylmethyl)amine}(PPh3)2]Cl. Reaction with potassium tert-butoxide at room temperature yields the unusual ruthenaziridine complex RuH{κ3CalkNNpy-1,3-di-(2-pyridylmethyl) amine}(PPh3)2, where the central nitrogen atom, adjacent alkyl carbon, and pyridine arm coordinate to the metal, leaving the second pyridine arm uncoordinated. Surprisingly, heating of this ruthenaziridine complex with concomitant H2 formation affords the ruthenium azaallyl complex RuH(κ3N-1,3-di-(2-pyridyl)-2-azaallyl)(PPh 3)2. This is a rare example of a 4d metal complex containing the azaallyl ligand. X-Ray crystal structures and NMR characterization of all three compounds are presented herein.

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