133886-50-7

Basic information

• Product Name: (3-Methoxymethoxy-2-methyl-butane-1-sulfonyl)-benzene
• CAS NO: 133886-50-7
• Molecular Weight: 272.365
• Mol File: 133886-50-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3-Methoxymethoxy-2-methyl-butane-1-sulfonyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (3-Methoxymethoxy-2-methyl-butane-1-sulfonyl)-benzene(133886-50-7)
• EPA Substance Registry System: (3-Methoxymethoxy-2-methyl-butane-1-sulfonyl)-benzene(133886-50-7)

Safety Data

• Hazardous Substances Data: 133886-50-7(Hazardous Substances Data)

Upstream product

• 133886-23-4 ((E)-1-Benzenesulfonyl-3-methoxymethoxy-but-1-enyl)-trimethyl-silane 
• 129083-19-8 (E)-1-benzenesulfonyl-1-buten-3-ol 

Downstream Products

• 133886-47-2 (2S,3R)-4-Benzenesulfonyl-3-methyl-butan-2-ol 
• 133886-47-2 (+/-)-(2R*,3R*)-3-methyl-4-(phenylsulfonyl)butan-2-ol 

Relevant articles and documents

Synthesis and conjugate additions to (E)-γ-alkoxy-α-substituted-α,β-unsaturated sulfones

(E)-γ-hydroxy-α,β-unsaturated sulfones have been readily functionalized at α-position via protection of hydroxyl group, metalation with n-BuLi and subsequent reaction with electrophiles. The conjugate addition of organolithiums to (E)-γ-methoxymethoxy-α-trimethylsilyl-α,β-unsaturated phenyl sulfones in Et2O is highly syn-stereoselective