129083-19-8

Upstream product

• 129083-18-7 (+/-)-(phenylsulfonyl)(p-tolylsulfinyl)methane 
• 123-38-6 propionaldehyde 
• 133445-41-7 <(p-chlorophenyl)sulfinyl>(phenylsulfonyl)methane 
• 54384-18-8 1-phenylsulfinyl-1-phenylsulfonylmethane 
• 3112-85-4 methylphenylsulfonate 
• 71804-85-8 ((4-chlorophenyl)thio)methyl phenyl sulfone 
• 7205-98-3 chloromethyl phenyl sulfone 
• 100-68-5 methyl-phenyl-thioether 
• 15296-86-3 1-(phenylsulfanyl)methyl phenyl sulfone 
• 618-41-7 Benzenesulfinic acid 
• 128565-04-8 2-benzenesulfonylmethyl-3-methyl-oxirane 

Downstream Products

• 141088-33-7 Acetic acid (E)-(R)-3-benzenesulfonyl-1-methyl-allyl ester 
• 132016-57-0 (S)-(E)-4-(phenylsulfonyl)-3-buten-2-ol 
• 135619-61-3 (E)-4-(phenylsulfonyl)-3-buten-2-yl 2-<(methoxycarbonyl)oxy>-3-<(trimethylsilyl)methyl>-3-butenoate 
• 21860-46-8 (E)-β-acetylvinyl phenyl sulphone 
• 194851-85-9 ethyl (E)-1-(phenylsulfonyl)-1-buten-3-yl carbonate 
• 586952-12-7 (E)-1-benzenesulfonyl-3-p-toluenesulfonylaminocarbonyloxy-1-butene 
• 133886-52-9 C₁₈H₂₂O₄S 
• 133886-52-9 C₁₈H₂₂O₄S 
• 133886-49-4 [(R)-2-((R)-1-Methoxymethoxy-ethyl)-hexane-1-sulfonyl]-benzene 
• 133886-49-4 [(R)-2-((S)-1-Methoxymethoxy-ethyl)-hexane-1-sulfonyl]-benzene 
• 133886-47-2 (+/-)-(2R*,3R*)-3-methyl-4-(phenylsulfonyl)butan-2-ol 
• 133886-47-2 (2S,3R)-4-Benzenesulfonyl-3-methyl-butan-2-ol 
• 133886-19-8 (E)-2-Benzenesulfonyl-4-methoxymethoxy-1-phenyl-pent-2-en-1-ol 
• 133886-21-2 (E)-2-Benzenesulfonyl-4-methoxymethoxy-pent-2-enoic acid ethyl ester 

Relevant academic research and scientific papers

Iodosulfonation of alkenes with benzenesulfinic acid - N-iodosuccinimide - Facile preparation of αβ-unsaturated sulfones

Reaction of alkenes and alkenols with N-iodosuccinimide (NIS) and benzenesulfinic acid in dichloromethane at room temperature affords vic-iodophenylsulfonyl adducts in good to high yields. Treatment of the iodosulfones with neutral alumina in dichlorometh

Stereoselective synthesis of trans-4,5-disubstituted oxazolidin-2-ones by intramolecular conjugate addition of N-p-toluenesulfonyl carbamates

p-Toluenesulfonyl carbamates (2a-d) were prepared starting from allylic alcohols (3), in which the double bond is conjugated with an electron withdrawing group. In the presence of a catalytic amount of DBU, an intramolecular cyclisation occurred, leading

Control of Diastereofacial Selectivity in the Nucleophilic Epoxidation of γ-Oxygenated α,β-Unsaturated Sulfones

Epoxidation of γ-oxygenated-α,β-unsaturated sulfones 6-10 with either lithium or potassium tert-butyl peroxide proceeds with moderate to high diastereoselectivity to give mixtures of the syn-2-(phenylsulfonyl)oxiranes 11-15 and the corresponding anti-2-(p

A practical route to (E)-γ-hydroxy-αβ-unsaturated phenyl sulfones

Reaction of enolizable aldehydes with p-tolylsulfinylmethyl phenyl sulfone (1) in the presence of piperidine in acetonitrile gave selectively E-γ-hydroxy-αβ-unsaturated phenyl sulfones (2) in good yields. Reaction from enantiomerically pure sulfoxide 1 gave unsaturated sulfones 2 in moderate optical yields (ee= 10-50%).

Facile synthesis of E-γ-hydroxy-α,β-unsaturated sulfones from aldehydes

Reaction of enolizable aldehydes with p-tolylsulfinylmethyl phenyl sulfone (1), in the presence of piperidine in acetonitrile at 0°C, gave selectively E-γ-hydroxy-α,β-unsaturated phenyl sulfones in good yields.