129083-19-8

Basic information

• Product Name: 3-Buten-2-ol, 4-(phenylsulfonyl)-, (E)-
• CAS NO: 129083-19-8
• Molecular Formula: C10H12O3S
• Molecular Weight: 212.269
• Mol File: 129083-19-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3-Buten-2-ol, 4-(phenylsulfonyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Buten-2-ol, 4-(phenylsulfonyl)-, (E)-(129083-19-8)
• EPA Substance Registry System: 3-Buten-2-ol, 4-(phenylsulfonyl)-, (E)-(129083-19-8)

Safety Data

• Hazardous Substances Data: 129083-19-8(Hazardous Substances Data)

Upstream product

• 129083-18-7 (+/-)-(phenylsulfonyl)(p-tolylsulfinyl)methane 
• 123-38-6 propionaldehyde 
• 3112-85-4 methylphenylsulfonate 
• 71804-85-8 ((4-chlorophenyl)thio)methyl phenyl sulfone 
• 7205-98-3 chloromethyl phenyl sulfone 
• 100-68-5 methyl-phenyl-thioether 
• 15296-86-3 1-(phenylsulfanyl)methyl phenyl sulfone 
• 618-41-7 Benzenesulfinic acid 
• 128565-04-8 2-benzenesulfonylmethyl-3-methyl-oxirane 
• 54384-18-8 1-phenylsulfinyl-1-phenylsulfonylmethane 
• 133445-41-7 <(p-chlorophenyl)sulfinyl>(phenylsulfonyl)methane 

Downstream Products

• 146231-58-5 5-methyl-3-(phenylsulfonyl)-2(5H)-furanone 
• 146231-56-3 (E)-4-(methoxymethoxy)-2-(phenylsulfonyl)-2-pentenoic acid 
• 146231-57-4 (E)-methyl 4-(methoxymethoxy)-2-(phenylsulfonyl)-2-pentanoate 
• 133886-52-9 C₁₈H₂₂O₄S 
• 133886-52-9 C₁₈H₂₂O₄S 
• 133886-49-4 [(R)-2-((R)-1-Methoxymethoxy-ethyl)-hexane-1-sulfonyl]-benzene 
• 133886-49-4 [(R)-2-((S)-1-Methoxymethoxy-ethyl)-hexane-1-sulfonyl]-benzene 
• 133886-47-2 (+/-)-(2R*,3R*)-3-methyl-4-(phenylsulfonyl)butan-2-ol 
• 133886-47-2 (2S,3R)-4-Benzenesulfonyl-3-methyl-butan-2-ol 
• 133886-19-8 (E)-2-Benzenesulfonyl-4-methoxymethoxy-1-phenyl-pent-2-en-1-ol 
• 133886-21-2 (E)-2-Benzenesulfonyl-4-methoxymethoxy-pent-2-enoic acid ethyl ester 
• 133886-20-1 (E)-5-Benzenesulfonyl-7-methoxymethoxy-4-methyl-oct-5-en-4-ol 
• 133886-23-4 ((E)-1-Benzenesulfonyl-3-methoxymethoxy-but-1-enyl)-trimethyl-silane 
• 133886-54-1 [(S)-2-((R)-1-Methoxymethoxy-ethyl)-3,3-dimethyl-butane-1-sulfonyl]-benzene 

Relevant articles and documents

Iodosulfonation of alkenes with benzenesulfinic acid - N-iodosuccinimide - Facile preparation of αβ-unsaturated sulfones

Reaction of alkenes and alkenols with N-iodosuccinimide (NIS) and benzenesulfinic acid in dichloromethane at room temperature affords vic-iodophenylsulfonyl adducts in good to high yields. Treatment of the iodosulfones with neutral alumina in dichlorometh

Control of Diastereofacial Selectivity in the Nucleophilic Epoxidation of γ-Oxygenated α,β-Unsaturated Sulfones

Epoxidation of γ-oxygenated-α,β-unsaturated sulfones 6-10 with either lithium or potassium tert-butyl peroxide proceeds with moderate to high diastereoselectivity to give mixtures of the syn-2-(phenylsulfonyl)oxiranes 11-15 and the corresponding anti-2-(p

A practical route to (E)-γ-hydroxy-αβ-unsaturated phenyl sulfones

Reaction of enolizable aldehydes with p-tolylsulfinylmethyl phenyl sulfone (1) in the presence of piperidine in acetonitrile gave selectively E-γ-hydroxy-αβ-unsaturated phenyl sulfones (2) in good yields. Reaction from enantiomerically pure sulfoxide 1 gave unsaturated sulfones 2 in moderate optical yields (ee= 10-50%).