133962-62-6

Basic information

• Product Name: (1RS,2RS,4SR)-1,4,5,6,7,7-hexachlorobicyclo<2.2.1>hept-5-en-2-ol
• CAS NO: 133962-62-6
• Molecular Weight: 316.826
• Mol File: 133962-62-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1RS,2RS,4SR)-1,4,5,6,7,7-hexachlorobicyclo<2.2.1>hept-5-en-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1RS,2RS,4SR)-1,4,5,6,7,7-hexachlorobicyclo<2.2.1>hept-5-en-2-ol(133962-62-6)
• EPA Substance Registry System: (1RS,2RS,4SR)-1,4,5,6,7,7-hexachlorobicyclo<2.2.1>hept-5-en-2-ol(133962-62-6)

Safety Data

• Hazardous Substances Data: 133962-62-6(Hazardous Substances Data)

Upstream product

• 108-05-4 vinyl acetate 
• 19095-29-5 (1RS,2RS,4SR)-1,4,5,6,7,7-hexachlorobicyclo<2.2.1>hept-5-en-2-ol 
• 77-47-4 hexachlorocyclopentadiene 
• 19095-28-4 1,2,3,4,7,7-Hexachlor-5endo-acetoxy-bicylo<2.2.1>hepten-(2) 
• 36170-00-0 2-(1,4,5,6,7,7-hexachloro-norborn-5-en-2endo-yl)-[1,3,2]dioxaborolane 

Downstream Products

• 19095-28-4 Acetic acid (1R,2R,4S)-1,4,5,6,7,7-hexachloro-bicyclo[2.2.1]hept-5-en-2-yl ester 
• 19095-28-4 5-Acetoxy-hexachlor-5,6,6H-bicyclo<2.2.1>hept-2-en 
• 19095-29-5 endo-1,4,5,6,7,7-Hexachlor-norborn-5-en-2-ol 
• 89642-41-1 1,4,5,6,7,7-Hexachlorbicyclo<2.2.1>hept-5-en-2-on 

Relevant articles and documents

ENZYMATIC ACYLATION USING ACID ANHYDRIDES: CRUCIAL REMOVAL OF ACID

An efficient enzymatic resolution of 7,7-disubstituted 1,4,5,6-tetrachlorobicyclohept-5-en-2-ols was accomplished by means of lipase AY-30 from Candida cylindracea in toluene.When acid anhydrides were used as acyl donors, the enantioselectivity was found to depend strongly on the reaction conditions: Whereas low selectivity (E 200).Alternatively, adsorption of the biocatalyst onto Celite was equally effective (E >300).Complete specificity was obtained when vinyl acetate was used as acyl donor (E ca.1000).