133967-46-1

Basic information

• Product Name: methyl bicyclo<3.1.0>hex-6-syn-ylacetate
• CAS NO: 133967-46-1
• Molecular Weight: 154.209
• Mol File: 133967-46-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl bicyclo<3.1.0>hex-6-syn-ylacetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl bicyclo<3.1.0>hex-6-syn-ylacetate(133967-46-1)
• EPA Substance Registry System: methyl bicyclo<3.1.0>hex-6-syn-ylacetate(133967-46-1)

Safety Data

• Hazardous Substances Data: 133967-46-1(Hazardous Substances Data)

Upstream product

• 36850-80-3 [(1-methoxyvinyl)oxy]trimethylsilane 
• 76644-52-5 rac-3-acetoxycyclohexene 

Relevant articles and documents

The Regio- and Stereoselectivities of the Reaction of Allyl Acetates and Silyl Ketene Acetals Catalyzed by Pd(0) Complexes: A New Route to Cyclopropane Derivatives

Pd(0) complexes of chelating phosphines catalyzed the coupling of allyl acetates and ketene silyl acetals to yield α-allylated carboxylic acid esters.Unexpectedly alkylation of the central carbon atom (C2) of the allyl groups was also observed with concomitant formation of cyclopropane derivatives.In both cases the silyl enolate attacked the allyl group from the side opposite Pd.The yield of the reaction was sensitive to the nature of the ligand coordinated with palladium.The 1,1'-bis(diphenylphosphino)ferrocene-Pd complex was the most effective catalyst.