1339707-20-8Relevant articles and documents
Mechanistic switch in dual gold catalysis of diynes: C(sp3)-H activation through bifurcation - Vinylidene versus carbene pathways
Hansmann, Max M.,Rudolph, Matthias,Rominger, Frank,Hashmi, A. Stephen K.
supporting information, p. 2593 - 2598 (2013/03/29)
The other side of the mountain: Changing the framework of diyne systems opens up new cyclization modes for dual gold catalysis. Instead of a 5-endo cyclization and gold vinylidenes a 6-endo cyclization gives rise to gold-stabilized carbenes as key intermediates for selective C-H insertions. Copyright