1339947-99-7Relevant academic research and scientific papers
Sequential deoxyfluorination approach for the synthesis of protected α,β,γ-trifluoro-δ-amino acids
Cheerlavancha, Raju,Lawer, Aggie,Cagnes, Marina,Bhadbhade, Mohan,Hunter, Luke
supporting information, p. 5562 - 5565 (2013/11/19)
Backbone-homologated amino acids have been synthesized, containing three vicinal fluorine atoms placed stereospecifically along the carbon chain. Different trifluoro stereoisomers are found to have contrasting conformations, consistent with known stereoel
Kinetic resolution of allylic alcohols via stereoselective acylation catalyzed by lipase PS-30
Chen, Peiran,Xiang, Peng
experimental part, p. 5758 - 5760 (2011/12/03)
By using lipase PS-30 as catalyst, the kinetic resolution of a series of racemic allylic alcohols has been achieved via stereoselective acylation. The value of kinetic enantiomeric ratio (E) reached up to 968. Substituent effect is briefly discussed.
