134024-35-4Relevant academic research and scientific papers
Fluoride Ion Promoted Anodic Substitutions of Chalcogeno Compounds. 1. Regioselective Anodic Alkoxylation of Sulfides
Fuchigami, Toshio,Yano, Hidetoshi,Konno, Akinori
, p. 6731 - 6733 (2007/10/02)
Anodic α-alkoxylation of sulfides was remarkably promoted in the presence of fluoride ions: When Et3N*3HF was used as a supporting electrolyte, simple alkyl phenyl sulfides and sulfides bearing weak electron-withdrawing groups underwent anodic alkoxylatio
Electrolytic reactions of fluoro organic compounds. 8. Further study on anodic methoxylation and acetoxylation of aryl fluoroalkyl sulfides
Fuchigami, Toshio,Yamamoto, Kayoko,Konno, Akinori
, p. 625 - 634 (2007/10/02)
Anodic α-methoxylation and α-acetoxylation of substituted phenyl 2,2.2-trifluoroethyl sulfides and various fluoroalkyl phenyl sulfides were studied from both synthetic and mechanistic aspects. These anodic reactions were greatly affected by both substituent groups at the benzene ring and fluoroalkyl groups. Electron-donating substituents interfered with the reactions significantly. Strong electron-withdrawing perfluoroalkyl groups(CnFn+1: N = 1-3) remarkably promoted these anodic substitutions while difluoro- and monofluoromethyl groups showed much less substitution.
