134029-38-2Relevant academic research and scientific papers
Thiolato Complexes of Monovalent Gold. Synthesis and Structure of 6 and (NH4)
Schroeter, Ingrid,Straehle, Joachim
, p. 2161 - 2164 (2007/10/02)
Reaction of Au(CO)Cl with 2,4,6-tri(isopropyl)thiophenol affords hexameric gold(I) thiolate 6 (1).According to an X-ray analysis 1 forms centrosymmetrical twelve-membered Au-S ring in the chair conformation with the linearly coordinated Au atoms at the mid-edges and the S atoms at the corners of the heterocycle.When the reaction of 2,4,6-tri(isopropyl)thiophenol is carried out with AuI in liquid ammonia the thiolato complex - - NH4+ (2) is obtained.It crystallizes as NH4 * 2 * 3NH3.The gold atom in 2 is linearly coordinated by two thiolato S atoms.The ammonium cation forms hydrogen bonds with three NH3 solvate molecules.Key Words: Gold(I) 2,4,6-tri(isopropyl)thiophenolate, hexamer / Aurate(I), bis
