134030-82-3

Basic information

• Product Name: 1,1-dimethoxy-3-phenyl-3-(phenylseleno)-2-propanone
• CAS NO: 134030-82-3
• Molecular Weight: 349.288
• Mol File: 134030-82-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1-dimethoxy-3-phenyl-3-(phenylseleno)-2-propanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-dimethoxy-3-phenyl-3-(phenylseleno)-2-propanone(134030-82-3)
• EPA Substance Registry System: 1,1-dimethoxy-3-phenyl-3-(phenylseleno)-2-propanone(134030-82-3)

Safety Data

• Hazardous Substances Data: 134030-82-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 10147-11-2 propargyl benzene 
• 1666-13-3 diphenyl diselenide 

Relevant articles and documents

Selenium-Mediated Conversion of Alkynes into α-Dicarbonyl Compounds

The reaction of terminal and internal alkynes with diphenyl diselenide and ammonium peroxydisulfate in methanol proceeds smoothly to give α-keto acetals and α-keto ketals, respectively.This one-pot procedure is suggested to proceed through the initial formation of phenylselenenyl sulfate, a strong electrophilic reagent which effects the methoxyselenenylation of the alkynes.The addition products thus formed suffer methoxydeselenenylation giving the observed products and regenerating the phenylselenenylating agent.In some cases the reaction can be carried out using only catalytic amounts of diphenyl diselenide.The same reaction carried out in the presence of water or of ethylene glycol gives the unprotected or the diprotected α-dicarbonyl compounds, respectively.