134040-39-4

Basic information

• Product Name: α-D-glucofurano<1,2-d>oxazolidin-2-one
• CAS NO: 134040-39-4
• Molecular Weight: 205.167
• Mol File: 134040-39-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: α-D-glucofurano<1,2-d>oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: α-D-glucofurano<1,2-d>oxazolidin-2-one(134040-39-4)
• EPA Substance Registry System: α-D-glucofurano<1,2-d>oxazolidin-2-one(134040-39-4)

Safety Data

• Hazardous Substances Data: 134040-39-4(Hazardous Substances Data)

Upstream product

• 124-38-9 carbon dioxide 
• 20379-60-6 α-D-Glucopyranosyl azide 

Downstream Products

• 285568-38-9 2,2-Dimethyl-propionic acid (3aS,5R,6S,6aR)-5-[(R)-1,2-bis-(2,2-dimethyl-propionyloxy)-ethyl]-2-oxo-3-phenylacetyl-hexahydro-furo[2,3-d]oxazol-6-yl ester 

Relevant articles and documents

Studies of the synthesis of 1,2-cis-(cyclic carbamates) of α-D-aldopyranosylamines

Reaction of α-D-glucopyranosyl azide with triphenylphosphine and carbon dioxide gave 1-N,2-O-carbonyl-α-D-glucopyranosylamine (7) and its α-D-furanose analogue (1), and 1-N,3-O-carbonyl-α-D-allofuranosylamine (15) and its α-D-pyranose analogue (17).Similarly, α-D-xylopyranosyl azide gave 1-N,2-O-carbonyl-α-D-xylopyranosylamine (9) and its α-D-furanose analogue (3), and 1-N,3-O-carbonyl-α-D-ribopyranosylamine (19) and its β-D-xylopyranose analogue (21).The structures of the products and their acetylated derivatives were established by 1H and 13C NMR spectroscopy. 1-N,3-O-Carbonyl-β-D-xylopyranosylamine (21) was obtained from β-D-xylopyranosyl azide when spontaneous rearrangement of the 1,2-(cyclic carbamate) 5 into 21 occurred in water.