1341127-82-9Relevant academic research and scientific papers
Direct access to β-oxodiazo compounds by copper(II)-catalyzed oxidative rearrangement of stabilized vinyl diazo derivatives
Barluenga, Jose,Lonzi, Giacomo,Riesgo, Lorena,Tomas, Miguel,Lopez, Luis A.
supporting information; experimental part, p. 18138 - 18141 (2011/12/21)
The copper(II)-catalyzed reaction of alkenyldiazo compounds with iodosylbenzene leading to β-oxodiazo derivatives is reported. This process occurs via an unprecedented 1,2-shift of the diazoacetate function. A selection of the synthetic applications of a
