134150-28-0Relevant academic research and scientific papers
2,4-Dimethylmethano-2,4-didehydroamantane and its reactivity in relation to the unsubstituted analogue
Mlinaric-Majerski,Safar-Cvitas,Majerski
, p. 1655 - 1658 (1991)
2,4-Dimethylmethano-2,4-didehydroadamantane (1) has been prepared and the gem-dimethyl substituent effects of propellane 1 in relation to its unsubstituted analogue 2 were studied. The reactivity of 1 is considerably greater than that of 2 due to the higher nucleophilicity of its central bond. However, 1 is thermally more stable than 2.
