Tetrahedron Letters p. 1655 - 1658 (1991)
Update date:2022-08-04
Topics:
Mlinaric-Majerski
Safar-Cvitas
Majerski
2,4-Dimethylmethano-2,4-didehydroadamantane (1) has been prepared and the gem-dimethyl substituent effects of propellane 1 in relation to its unsubstituted analogue 2 were studied. The reactivity of 1 is considerably greater than that of 2 due to the higher nucleophilicity of its central bond. However, 1 is thermally more stable than 2.
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