1342445-09-3

Basic information

• Product Name: methyl 3-(2,6-difluorophenyl)propiolate
• Synonyms: methyl 3-(2,6-difluorophenyl)propiolate
• CAS NO: 1342445-09-3
• Molecular Weight: 196.153
• Mol File: 1342445-09-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 3-(2,6-difluorophenyl)propiolate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-(2,6-difluorophenyl)propiolate(1342445-09-3)
• EPA Substance Registry System: methyl 3-(2,6-difluorophenyl)propiolate(1342445-09-3)

Safety Data

• Hazardous Substances Data: 1342445-09-3(Hazardous Substances Data)

Upstream product

• 13697-89-7 2,6-difluoroiodobenzene 
• 922-67-8 propynoic acid methyl ester 
• 437-81-0 2,6-difluorobenzaldehyde 
• 79-22-1 methyl chloroformate 
• 18107-18-1 diazomethyl-trimethyl-silane 

Downstream Products

• 1361019-10-4 5-(2,6-difluorophenyl)-1,2-dihydro-1-methyl-3H-pyrazol-3-one 
• 1361019-11-5 5-(2,6-difluorophenyl)-3-methoxy-1-methyl-1H-pyrazole 
• 1361019-12-6 5-(2,6-difluorophenyl)-3-methoxy-1-methyl-1H-pyrazole-4-carboxaldehyde 
• 1361021-00-2 5-(2,6-difluorophenyl)-α-(4-fluoro-2-methylphenyl)-3-methoxy-1-methyl-1H-pyrazole-4-methanol 

Relevant articles and documents

Synthesis and Characterization of Bidentate (P^N)Gold(III) Fluoride Complexes: Reactivity Platforms for Reductive Elimination Studies

A new family of cationic, bidentate (P^N)gold(III) fluoride complexes has been prepared and a detailed characterization of the gold-fluoride bond has been carried out. Our results correlate with the observed reactivity of the fluoro ligand, which undergoes facile exchange with both cyano and acetylene nucleophiles. The resulting (P^N)arylgold(III)C(sp) complexes have enabled the first study of reductive elimination on (P^N)gold(III) systems, which demonstrated that C(sp2)?C(sp) bond formation occurs at higher rates than those reported for analogous phosphine-based monodentate systems.