134248-82-1

Basic information

• Product Name: 1,4-Benzenediamine, N-(4-aminophenyl)-N-(4-methoxyphenyl)-
• CAS NO: 134248-82-1
• Molecular Formula: C19H19N3O
• Molecular Weight: 305.379
• Mol File: 134248-82-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1,4-Benzenediamine, N-(4-aminophenyl)-N-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Benzenediamine, N-(4-aminophenyl)-N-(4-methoxyphenyl)-(134248-82-1)
• EPA Substance Registry System: 1,4-Benzenediamine, N-(4-aminophenyl)-N-(4-methoxyphenyl)-(134248-82-1)

Safety Data

• Hazardous Substances Data: 134248-82-1(Hazardous Substances Data)

Upstream product

• 104-94-9 4-methoxy-aniline 
• 350-46-9 4-Fluoronitrobenzene 

Downstream Products

• 1226915-29-2 4,4'-di(4-hydroxybenzylideneamino)-4''-methoxytriphenylamine 
• 1350929-65-5 4,4'-bis[(4-aminophenyl)amino]-4''-methoxytriphenylamine 
• 1350929-64-4 4,4′-bis[(4-nitrophenyl)amine]-4″-methoxytriphenylamine 

Relevant articles and documents

Novel triphenylamine-based polyamides: Efficient preparation via benzoxazine-isocyanide-chemistry at room temperature and electrochromic properties investigation

A type of novel triphenylamine (TPA)-based diisocyanide derivative, 4-isocyano-N-(4-isocyanophenyl)-N-(4-methoxyphenyl)aniline (M1), was successfully synthesized via Hofmann treatment of its primary amine precursor (2). A series of polyamides (P1–P3), whi

Electrochromism properties of polyimides possessing triphenylamine moieties with different substituents

Two diamine monomers with methyl (CH3TPA) and methoxy (OCH3TPA) group substituents in the para position of the triphenylamine (TPA) moiety were synthesized by nucleophilic aromatic substitution using 4-fluoronitrobenzene with p-toluidine and p-anisidine,

Novel anodic electrochromic aromatic polyamides with multi-stage oxidative coloring based on N,N,N′,N′-tetraphenyl-p-phenylenediamine derivatives

A series of novel aromatic polyamides with pendent 4,4′-dimethoxy- substituted triphenylamine (TPA) units were prepared via the direct phosphorylation polycondensation from a new dicarboxylic acid monomer, N,N-bis(4-carboxyphenyl)-N′,N′-di(4-methoxyphenyl)-1, 4-phenylenediamine (4), and various aromatic diamines. These polyamides were amorphous with good solubility in many organic solvents, such as N-methyl-2-pyrrolidinone (NMP) and N,N-dimethylacetamide (DMAc), and could be solution-cast into flexible polymer films. They had excellent levels of thermal stability associated with their relatively high glass-transition temperatures (233-308 °C). These polymers exhibited strong UV-vis absorption bands at 351-363 nm in NMP solution. Their photoluminescence spectra showed maximum bands around 450-504 nm. The hole-transporting and electrochromic properties are examined by electrochemical and spectroelectrochemical methods. Cyclic voltammograms of the polyamide 6g prepared from the dicarboxylic acid monomer (4) with a structurally similar diamine monomer N,N-bis(4-aminophenyl)-N′, N′-di(4-methoxyphenyl)-1,4-phenylenediamine (5g) exhibited four reversible oxidation redox couples in acetonitrile solution at Eonset = 0.35, E1/2 = 0.64, 0.84, and 0.99 V, respectively. After over 3000 cyclic switches for green color, the films of polyamide 6g still showed excellent continuous cyclic stability of electrochromism.