134256-62-5Relevant academic research and scientific papers
High-pressure Synthesis, Structure and Novel Photochemical Reactions of 7,7,8,8-Tetramethyl-7,8-disilabicycloocta-2,5-diene
Sekiguchi, Akira,Maruki, Ikutaro,Ebata, Keisuke,Kabuto, Chizuko,Sakurai, Hideki
, p. 341 - 343 (2007/10/02)
7,7,8,8-Tetramethyl-7,8-disilabicycloocta-2,5-diene 1, prepared by the high-pressure reaction (10000 bar) of 1,1,2,2-tetramethyl-1,2-disilacyclohexa-3,5-diene and phenyl vinyl sulphoxide followed by elimination of benzenesulphenic acid, gave tetramethyldisilene (Me2Si=SiMe2) upon photolysis which underwent a photochemical reaction with benzene at 10 K in an argon matrix to regenerate the precursor.
