1342819-69-5Relevant academic research and scientific papers
Computer-Assisted Design of Ionic Liquids for Efficient Synthesis of 3(2H)-Furanones: A Domino Reaction Triggered by CO2
Chen, Kaihong,Shi, Guiling,Zhang, Weidong,Li, Haoran,Wang, Congmin
, p. 14198 - 14201 (2016)
A strategy for the highly efficient synthesis of 3(2H)-furanones by hydration of diyne alcohols catalyzed by base-functionalized ionic liquids under atmospheric-pressure CO2 that was developed through computer-assisted design is reported. The best range of basic ionic liquids as catalysts was predicted at first, and [HDBU][BenIm] exhibited the highest catalytic activity. Through a combination of NMR spectroscopic investigations and quantum-chemical calculations, the results indicated the importance of the basicity of the anion and the species of cation in the ionic liquid.
Carbon dioxide-mediated synthesis of 3(2H)-furanones from diyne alcohols
Yuan, Gaoqing,He, Zaijun,Zheng, Junhua,Chen, Zhengwang,Huang, Huawen,Shi, Dabin,Qi, Chaorong,Jiang, Huanfeng
, p. 5956 - 5959 (2011/11/28)
A novel type of carbon dioxide-mediated reaction of diyne alcohols without any metal catalysts was reported. Carbon dioxide held the key to the success of this reaction, in which 3(2H)-furanones were selectively obtained in moderate to high yields.
