1342879-17-7Relevant academic research and scientific papers
Catalytic palladium phosphination: Modular synthesis of C 1-symmetric biaryl-based diphosphines
Bonnafoux, Laurence,Gramage-Doria, Rafael,Colobert, Francoise,Leroux, Frederic R.
, p. 11008 - 11016 (2011/10/19)
A new family of C1-symmetric bis(diphenylphosphino)biphenyls have been prepared starting from readily available ortho,ortho′- dihalobiphenyl precursors by a palladium-catalyzed C-P coupling reaction. This process does not require the use of an
Bromine-lithium exchange: An efficient tool in the modular construction of biaryl ligands
Bonnafoux, Laurence,Leroux, Frederic R.,Colobert, Francoise
supporting information; experimental part, p. 1278 - 1287 (2011/10/31)
Regioselective bromine-lithium exchange reactions on polybrominated biaryls enable the modular synthesis of various polysubstituted biphenyls such as bis(dialkylphosphino)-, bis(diarylphosphino)- and dialkyl(diaryl) phosphinobiphenyls. All permutations of
