134329-59-2Relevant academic research and scientific papers
Rapid and stereoselective construction of dienediynes related to the neocarzinostatin chromophore
Bruckner,Scheuplein,Suffert
, p. 1449 - 1452 (1991)
Formylcyclopentanone was transformed into Z configuration dienediynes 15 in three steps. As the key step served Pd catalyzed stereoselective couplings of the isomerically pure bis(enoltriflate) 13 with two equiv. of alkyne.
