134341-47-2

Upstream product

• 134341-47-2 (1R,2R,3S,6R)-3,6-Bis-(tert-butyl-diphenyl-silanyloxy)-cyclohexane-1,2-diol 
• 134341-56-3 meso-(2R,5S)-2,5-bis(tert-butyldiphenylsilyloxy)hexane-1,6-dial 

Downstream Products

• 134341-56-3 meso-(2R,5S)-2,5-bis(tert-butyldiphenylsilyloxy)hexane-1,6-dial 
• 134522-14-8 meso-(1R,2S,3S,6R)-3,6-bis(tert-butyldiphenylsilyloxy)cyclohexane-1,2-diol 
• 134341-47-2 (1S,2R,3S,6R)-3,6-Bis-(tert-butyl-diphenyl-silanyloxy)-cyclohexane-1,2-diol 

Relevant academic research and scientific papers

The stereocontrolled formation of cyclic vicinal cis-diols via a samarium diiodide pinacol coupling of dialdehydes

Aliphatic 1,5- and 1,6 dialdehydes with and without α-substituents, as well as derivatives of carbohydrate dialdehydes undergo a pinacol coupling reaction in the presence of SmI2 to give cis-diols as the preponderant products. When α-alkoxy groups are present, the diol has an orientation that is opposite to such groups.