1343516-31-3Relevant academic research and scientific papers
Iron(II) chloride catalyzed alkylation of propargyl ethers: Direct functionalization of an sp3 C-H bond adjacent to oxygen
Xie, Yongju,Yu, Ming,Zhang, Yuhong
supporting information; experimental part, p. 2803 - 2809 (2011/10/09)
Iron(II) chloride catalyzed direct alkylation of sp3 C-H bond adjacent to oxygen in propargyl ethers has been accomplished by the use of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) as oxidant under mild reaction conditions. The reaction proceeded smoothly with a variety of 1,3-diketones leading to -dicarbonyl ether in moderate yields. In the absence of 1,3-diketones, ynenones were produced by the use of iron(III) chloride and DDQ. Georg Thieme Verlag Stuttgart - New York.
