134398-79-1Relevant academic research and scientific papers
TRIHYDROCARBYLTIN COMPLEXES OF TRANSITION METAL CYANIDES
Uson, R.,Fornies, J.,Uson, M. A.,Lalinde, E.
, p. 359 - 366 (1980)
Cationic single-bridged trinuclear cyano complexes are obtained by treating trihydrocarbyltin perchlorate (SnR3O2ClO2) (R=alkyl or aryl) with neutral transition metal monocyanides, whereas treatment with the corresponding neutral or anionic transition metal polycyanides gives neutral single-bridged polymeric cyano compounds.In every case the tin atoms are pentacoordinated with the three R groups in the equatorial and two CN groups (or, respectively one CN and one OClO3 group) in the axial position of a trigonal bipyramid.
