Journal of Organometallic Chemistry p. 359 - 366 (1980)
Update date:2022-08-04
Topics:
Uson, R.
Fornies, J.
Uson, M. A.
Lalinde, E.
Cationic single-bridged trinuclear cyano complexes are obtained by treating trihydrocarbyltin perchlorate (SnR3O2ClO2) (R=alkyl or aryl) with neutral transition metal monocyanides, whereas treatment with the corresponding neutral or anionic transition metal polycyanides gives neutral single-bridged polymeric cyano compounds.In every case the tin atoms are pentacoordinated with the three R groups in the equatorial and two CN groups (or, respectively one CN and one OClO3 group) in the axial position of a trigonal bipyramid.
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