134435-27-1

Basic information

• Product Name: (2-bromo-3-methoxyphenyl)diphenylphosphine oxide
• Synonyms: (2-bromo-3-methoxyphenyl)diphenylphosphine oxide
• CAS NO: 134435-27-1
• Molecular Weight: 387.213
• Mol File: 134435-27-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-bromo-3-methoxyphenyl)diphenylphosphine oxide(CAS DataBase Reference)
• NIST Chemistry Reference: (2-bromo-3-methoxyphenyl)diphenylphosphine oxide(134435-27-1)
• EPA Substance Registry System: (2-bromo-3-methoxyphenyl)diphenylphosphine oxide(134435-27-1)

Safety Data

• Hazardous Substances Data: 134435-27-1(Hazardous Substances Data)

Upstream product

• 95278-09-4 (3-methoxylphenyl)diphenylphosphine oxide 
• 1079-66-9 chloro-diphenylphosphine 
• 13145-84-1 (3-methoxyphenyl)(diphenyl)phosphane 
• 2398-37-0 3-methoxyphenyl bromide 

Downstream Products

• 1332483-72-3 3-methoxy-5-phenyl-5H-dibenzophosphole 5-oxide 
• 133545-15-0 (Sa)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine oxide) 
• 133545-15-0 (Ra)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine oxide) 
• 133545-16-1 (-)-(S)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) 
• 133545-16-1 (+)-(R)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) 
• 133545-16-1 (RS)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) 
• 133545-15-0 (RS)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine oxide) 

Relevant articles and documents

Axially Dissymmetric Diphosphines in the Biphenyl Series: Synthesis of (6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) ('MeO-BIPHEP') and Analogues via an ortho-Lithiation/Iodination Ullmann-Reaction Approach

The new axially dissymmetric diphosphines (R)- and (S)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) ((R)- and (S)-5a; 'MeO-BIPHEP') and the analogues (R)- and (S)-5b and 5c have been synthesized in enantiomerically pure form.These lignands hav