13444-14-9

Basic information

• Product Name: 3-Allylbenzoxazol-2(3H)-one
• Synonyms: 3-Allylbenzoxazol-2(3H)-one
• CAS NO: 13444-14-9
• Molecular Formula: C10H9NO2
• Molecular Weight: 175.184
• Mol File: 13444-14-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 271.6°Cat760mmHg
• Flash Point: 118°C
• Appearance: /
• Density: 1.197g/cm³
• Vapor Pressure: 0.0064mmHg at 25°C
• Refractive Index: 1.572
• CAS DataBase Reference: 3-Allylbenzoxazol-2(3H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Allylbenzoxazol-2(3H)-one(13444-14-9)
• EPA Substance Registry System: 3-Allylbenzoxazol-2(3H)-one(13444-14-9)

Safety Data

• Hazardous Substances Data: 13444-14-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H9NO2/c1-2-7-11-8-5-3-4-6-9(8)13-10(11)12/h2-6H,1,7H2

Upstream product

• 59-49-4 2-Benzoxazolinone 
• 107-18-6 allyl alcohol 
• 100-65-2 N-Phenylhydroxylamine 
• 117531-28-9 N-allyl-N-(phenyl)hydroxylamine 
• 76-02-8 trifluoroacetyl chloride 
• 106-95-6 allyl bromide 
• 15022-08-9 diallylcarbonate 
• 95-55-6 2-amino-phenol 

Relevant articles and documents

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Palladium-Catalyzed Dehydrative Cross-Coupling of Allylic Alcohols and N-Heterocycles Promoted by a Bicyclic Bridgehead Phosphoramidite Ligand and an Acid Additive

A mild and efficient dehydrative cross-coupling reaction between allylic alcohols and N-heterocycles using palladium catalysis is reported. A bicyclic bridgehead phosphoramidite (briphos) ligand together with Pd(dba)2 is a highly efficient catalyst, and an acid additive involved in the rate-determining step promotes the catalytic cycle. The coupling reaction of allylic alcohols with N-heterocycles including imidazoles, benzimidazoles, and triazole proceeds under mild reaction conditions with high yields using Pd/briphos and pentafluorophenol.