134452-27-0Relevant academic research and scientific papers
Highly enantioselective Rh-catalyzed transfer hydrogenation of N-sulfonyl ketimines
Kwak, Se Hun,Lee, Sun Ah,Lee, Kee-In
experimental part, p. 800 - 804 (2010/10/21)
Several imine species comprising N-sulfinyl and N-sulfonyl ketimine, oxime, and enamine derivatives were subjected to asymmetric transfer hydrogenation in an azeotropic mixture of formic acid/triethylamine. Among them, the Rh-catalyzed transfer hydrogenat
Application of the aza-Achmatowicz oxidative rearrangement for the stereoselective synthesis of the Cassia and Prosopis alkaloid family
Leverett, Carolyn A.,Cassidy, Michael P.,Padwa, Albert
, p. 8591 - 8601 (2007/10/03)
cis-2-Methyl-6-substituted piperidin-3-ol alkaloids of the Cassia and Prosopis species are readily prepared by a combination of an aza-Achmatowicz oxidative rearrangement and dihydropyridone reduction followed by a stereoselective allylsilane addition to
An efficient preparation of optically active α-furfuryl amide by kinetic resolution using the modified Sharpless asymmetric epoxidation reagents
Zhou,Lu,Wang
, p. 2641 - 2654 (2007/10/02)
Kinetic resolution of α-furfuryl amide was first carried out by using the modified Sharpless asymmetric epoxidation reagent to give the slow-reacting enantiomers, (S)-1(a-h) and (R)-1(b,f) in high enantioselectivity (90-100% e.e) and high chemical yield (
An efficient preparation of optically active α-furfuryl amide by kinetic resolution using the modified sharpless asymmetric epoxidation reagent
Zhou, Wei-Shan,Lu, Zhi-Hui,Wang, Zhi-Min
, p. 1467 - 1470 (2007/10/02)
Kinetic resolution of α-furfuryl amide was first carried out by using the modified Sharpless asymmetric epoxidation reagent to give the slow-reacting enantiomers, (S)-la-f and (R)-lb,f in high enantioselectivity (90-100% e.e) and high chemical yield (45-5
