134477-74-0Relevant academic research and scientific papers
Transformation of esters into 2-substituted allyl halides via tertiary cyclopropanols: Application in the stereoselective synthesis of (2S,3S,7S)-3,7-dimethyl-2-pentadecyl acetate, the sex pheromone of the pine sawfly Neodiprion sertifer
Bekish, Andrei V.,Prokhorevich, Konstantin N.,Kulinkovich, Oleg G.
, p. 5069 - 5075 (2007/10/03)
(2S,3S,7S)-3,7-Dimethyl-2-pentadecyl acetate (ac-1), the sex pheromone of the pine sawfly Neodiprion sertifer, has been newly synthesized by the transformation of the corresponding esters 8 and 12 into 2-oxyalkyl-substituted allyl bromides 4 and 5 via ter
4-SUBSTITUTED 2-AMINOALK-3-ENOIC ACIDS
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, (2008/06/13)
Substituted 2-aminoalk-3-enoic acid derivative of formula I STR1 wherein R 1 is an aliphatic hydrocarbon radical that is substituted by optionally acylated or aliphatically or araliphatically etherified hydroxy, by halogen, by optionally acylated and/or aliphatically substituted amino or by an aza-, diaza-, azoxa-or oxa-cycloaliphatic radical, or is an oxacycloaliphatic hydrocarbon radical bonded via a carbon atom, or is an optionally aliphatically N-substituted or N-acylated azacycloaliphatic hydrocarbon radical, and R. sub.2 is free or esterified carboxy, and their salts exhibit NMDA-antagonistic properties and are useful as active ingredients of anticonvulsive medicaments.
