920520-69-0Relevant articles and documents
Synthetic studies toward amphidinolide H1: Segment C14-C26
Deng, Lisheng,Ma, Zhixiong,Zhang, Yazhu,Zhao, Gang
, p. 87 - 90 (2008/03/13)
Stereoselective synthesis of the C14-C26 moiety of amphidinolide H1 is described. The key features of the approach include the convergent fragment assembly with a highly diastereoselective aldol reaction to establish the C18 stereochemistry and using comm
Transformation of esters into 2-substituted allyl halides via tertiary cyclopropanols: Application in the stereoselective synthesis of (2S,3S,7S)-3,7-dimethyl-2-pentadecyl acetate, the sex pheromone of the pine sawfly Neodiprion sertifer
Bekish, Andrei V.,Prokhorevich, Konstantin N.,Kulinkovich, Oleg G.
, p. 5069 - 5075 (2007/10/03)
(2S,3S,7S)-3,7-Dimethyl-2-pentadecyl acetate (ac-1), the sex pheromone of the pine sawfly Neodiprion sertifer, has been newly synthesized by the transformation of the corresponding esters 8 and 12 into 2-oxyalkyl-substituted allyl bromides 4 and 5 via ter