1345160-33-9

Upstream product

• 1908-61-8 4-bromo[2.2]paracyclophane 
• 1079-66-9 chloro-diphenylphosphine 
• 1289455-52-2 rac-P-(4-[2.2]paracyclophanyl)-P,P-diphenylphosphine oxide 

Downstream Products

• 1345160-37-3 rac-P-(4-(13-bromo[2.2]paracyclophanylene))-P,P-diphenylphosphine sulfide 
• 1345160-35-1 rac-P-(4-(13-bromo[2.2]paracyclophanylene))-P,P-diphenylphosphine 
• 1345160-42-0 rac-P-(4-(13-bromo[2.2]paracyclophanylene))-P,P-diphenylphosphineborane 
• 1345160-39-5 4,13-bis-(diphenylphosphino)-[2.2]paracyclophane 
• 1345160-30-6 4-diphenylphosphino-13-dicyclohexylphosphino-[2.2]paracyclophane 
• 1345160-46-4 4-diphenylphosphino-13-dicyclohexylphosphinoborane[2.2]paracyclophane 
• 1345160-50-0 4,13-bis(diphenylphosphino)[2.2]paracyclophane bisselenide 
• 1345160-53-3 4-diphenylphosphino-13-dicyclohexylphosphino[2.2]paracyclophane bisselenide 

Relevant academic research and scientific papers

Metal-to-Metal Distance Modulated Au(I)/Ru(II) Cyclophanyl Complexes: Cooperative Effects in Photoredox Catalysis

The modular synthesis of Au(I)/Ru(II) decorated mono- and heterobimetallic complexes with π-conjugated [2.2]paracyclophane is described. [2.2]Paracyclophane serves as a rigid spacer which holds the metal centers in precise spatial orientations and allows

Coupling of ortho-substituted aryl chlorides with bulky amides

Voluminous amides were coupled with deactivated, sterically hindered aryl chlorides in excellent yields providing products, which have not been efficiently accessible by transition metal catalysis so far. Application of an unsymmetric bisphosphine ligand was critical for the high catalytic activity.