1345262-71-6Relevant academic research and scientific papers
The catalytic asymmetric diels-alder reactions and post-cycloaddition reductive transpositions of 1-hydrazinodienes
Xie, Hao,Sammis, Glenn M.,Flamme, Eric M.,Kraml, Christina M.,Sorensen, Erik J.
, p. 11131 - 11134 (2011/11/05)
Cycling through: Type I cyclohexenes are produced with high margins of stereoselectivity by chiral, catalyst-controlled, Diels-Alder reactions between 1-hydrazinodienes and N-acryloyl oxazolidinone dienophiles, and readily transformed to cyclohexenes III via a putative, transient allylic diazene II (see scheme). This chemistry gives access to functionalized cyclohexenes that can be difficult to construct by alternative methods. Copyright
