1345295-48-8Relevant academic research and scientific papers
Synthesis of Thieno[3,2-b]indoles via Halogen Dance and Ligand-Controlled One-Pot Sequential Coupling Reaction
Hayashi, Yuki,Okano, Kentaro,Mori, Atsunori
, p. 958 - 961 (2018)
A two-pot synthesis of thieno[3,2-b]indole from 2,5-dibromothiophene is described. A halogen dance of 2,5-dibromothiophene was performed with LDA, and subsequent Negishi coupling was performed with 2-iodoaniline derivatives to provide the corresponding coupling products. The resulting two bromo groups have different reactivities, which were utilized for the one-pot Suzuki-Miyaura coupling/intramolecular Buchwald-Hartwig amination to produce thieno[3,2-b]indole via an assisted tandem catalysis that involved in situ ligand exchange.
NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
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, (2011/11/06)
Disclosed are organic electroluminescent compounds and organic electroluminescent devices employing said compounds. The organic electroluminescent compounds of the invention are substituted dihydro-pyrrolo[3,2-b:4,5-b']diindole, dihydro-furo[3,2-b:4,5-b']diindole and dihydro-thieno[3,2-b:4,5-b']diindole compounds defined by chemical formula (1), The compounds, when used in as a host material of an OLED device, exhibit good luminous efficiency and lifespan.
