134538-48-0

Basic information

• Product Name: 2-[(1E)-2-nitroprop-1-en-1-yl]furan
• Synonyms: 2-(2-nitro-1-propenyl)furan; 2-(2-Nitropropenyl)furan; 2-[(1E)-2-Nitro-1-propen-1-yl]furan; Furan, 2- (2-nitro-1-propenyl)-; Furan, 2- (2-nitropropenyl)-; Furan, 2-(2-nitro-1-propenyl)-; Furan, 2-(2-nitropropenyl)-; furan, 2-[(1E)-2-nitro-1-propen-1-yl]-
• CAS NO: 134538-48-0
• Molecular Formula: C₇H₇NO₃
• Molecular Weight: 153.1354
• Mol File: 134538-48-0.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 229.5°C at 760 mmHg
• Flash Point: 92.6°C
• Density: 1.217g/cm³
• Vapor Pressure: 0.105mmHg at 25°C
• Refractive Index: 1.553
• CAS DataBase Reference: 2-[(1E)-2-nitroprop-1-en-1-yl]furan(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(1E)-2-nitroprop-1-en-1-yl]furan(134538-48-0)
• EPA Substance Registry System: 2-[(1E)-2-nitroprop-1-en-1-yl]furan(134538-48-0)

Safety Data

• Hazardous Substances Data: 134538-48-0(Hazardous Substances Data)

Upstream product

• 98-01-1 furfural 
• 79-24-3 Nitroethane 
• 6975-60-6 1-furan-2-yl-propan-2-one 
• 98-00-0 (2-furyl)methyl alcohol 

Downstream Products

• 6975-60-6 1-furan-2-yl-propan-2-one 
• 57580-64-0 1-(2-furyl)-2-aminopropane 

Relevant articles and documents

A Convenient Synthesis of 1-(2-Furyl)-2-nitroalk-1-enes on Alumina Surface without Solvent

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Catalytic asymmetric Tamura cycloadditions involving nitroalkenes

The first examples of asymmetric Tamura cycloaddition reactions involving singly activated alkenes are reported. Homophthalic anhydride reacts with α-methyl nitrosytrenes in the presence of an alkaloid-based catalyst to generate fused bicyclic aromatic ketone products with three new stereocentres (which are susceptible to subsequent equilibration) in 12-99% ee. An unusual equilibration process which occurs in methanolic medium in the absence of a recognisable base via proton transfer at the α-carbon of an ester was investigated experimentally and computationally.

Palladium-catalyzed synthesis of substituted nitroolefins

A one-pot protocol toward several substituted nitroolefins 4 and 6 starting with substituted acetones 2 and 5 was described. A facile process was carried out for the triflation of substituted acetones 2 and 5 with triflic anhydride (Tf2O) under the basic condition (Cs2CO3) and then palladium-catalyzed cross-coupling of enol triflates 3 with NaNO 2 and BINAP in the presence of phase-transfer reagents (n-Bu 4NBr) under the refluxing 1,2-dimethoxyethane (DME) in acceptable yields.