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Usage

Uses

Used in Optoelectronics Industry:
Cesium perchlorate is used as a modifier for long-duration optical transmission of information with infofuses. Its properties enhance the performance and efficiency of these devices, making it a valuable component in this field.
Used in Polymer Science:
Cesium perchlorate serves as a modifier of polymer electrolyte/luminescent conjugated polymer mixed ionic-electronic conductors. This application takes advantage of its ability to improve the conductivity and performance of these materials, which are essential in various electronic devices.
Used in Material Science:
Cesium perchlorate is used in studies involving pH-dependent mass and volume changes of polypyrrole/poly(styrene sulfonate). Its role in these investigations helps to understand the behavior of these materials under different conditions, leading to potential advancements in material development.
Used in Electrochemistry:
Cesium perchlorate is utilized to study cationic effects in polymer light-emitting electrochemical cells. This research contributes to the development of more efficient and sustainable energy storage and conversion systems.
Used in Nanotechnology:
Cesium perchlorate acts as a reactant for investigating metal salt effects on the morphology of silica nanomaterials prepared by polymerization on hydrogels. This application highlights its importance in the development of advanced nanomaterials with tailored properties for various applications.
Used in Ionic Conductivity Research:
Cesium perchlorate is employed in investigations of ionic conductivity in orientationally disordered phases. This research helps to expand our understanding of ionic conduction in materials, which is crucial for the development of new technologies and applications in energy storage and conversion.

Purification Methods

Crystallise it from water (4mL/g) between 100o and 0o.

InChI:InChI=1/ClHO4.Cs/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

Upstream product

• 7601-90-3 perchloric acid 
• 18437-47-3 cesium cupric chloride 
• 15690-63-8 cesium chloride 
• 264619-02-5 caesium dimethylthiocarbamoylcyanoximate 
• 534-17-8 caesium carbonate 
• 7790-98-9 ammonium perchlorate 
• 13106-69-9 caesium methoxide 

Downstream Products

• 15690-63-8 cesium chloride 
• 7783-54-2 nitrogen trifluoride 
• 16949-12-5 cesium hexafluoroantimonate 
• 10049-03-3 chlorine tetroxide fluoride 
• 13706-14-4 NF₄⁽¹⁺⁾*ClO₄^(1-)=NF₄ClO₄ 

Relevant academic research and scientific papers

Conductometric, Viscometric, and Spectroscopic Investigations on the Solvation Phenomena of Alkali-Metal Ions and Ion Pairs in 2-Methoxyethanol

Precise measurements on electrical conductances, relative viscosities, and laser-Raman spectra of solutions of some alkali-metal salts in 2-methoxyethanol (ME) have been reported.The conductance data were analyzed by the 1978 Fuoss conductance equation an

An improved method for product separation in metathetical reactions and its demonstration for the synthesis of anhydrous cesium salts

In conventional metathetical reactions, product separation is based on solubility product differences, and the resulting products are often impure and require purification by recrystallization. A new approach to product separation is described that relies on the formation of an unstable, volatile by-product, such as NH4+CH3O-. This method provides very pure and anhydrous products in high yield and was demonstrated successfully for the syntheses of anhydrous cesium salts.

N,N-Dimethylthioamidecyanooximato Nickel(II) Complex Containing a Saturated Tetraamine Macrocycle, [Ni[13]aneN4{ONC(CN)C(S)N(CH3)2}]CIO 4: Synthesis, Spectra, and Structure

The complex Ni[13]aneN4){TDCO}]CIO4, where [13]aneN4 is 1,4,7,10-tetraazacyclotridecane, and {TDCO-} is N,N-dimethylthioamidecyanooximato ion {ONC(CN)C(S)N(CH3)2}-, was synthesized and characterized by IR and electronic spectroscopy and X-ray diffraction. The complex is triclinic, space group P1?, with a = 9.619(2) ?, b = 9.929(2) ?, c = 11.827(2) ?, α = 99.37(3)°, β = 97.71(3)°, γ = 95.99(3)°, Z = 2, V = 1095.2(4) ?3, pcalc = 1.518 g/cm3. The structure was refined to R = 0.057 and wR2 = 0.142. The structure is ionic and consists of Ni[13]aneN4){TDCO}]+ complex cations and ClO4- anions. The central atom has slightly distorted octahedral coordination. The acido ligand is coordinated through the nitroso nitrogen and thioamide sulfur to form a five-membered chelate ring (Ni-N 2.072(4) ?, Ni-S 2.389(2) ?). The tetraaza macrocycle adopts the bent conformation and is coordinated via four nitrogen atoms, two in the equatorial plane and two in axial positions (Ni-N 2.069(4)-2.139(4) ?).

Transfer Gibbs energies for ClO3-, BrO3-, IO3-, ClO4- and IO4- anions for water-methanol and water-propan-2-ol mixtures: Some quantum-chemical aspects of ionic solvation

The transfer Gibbs energies, ΔtrsG°, of KClO3, KBrO3, KIO3, KClO4, KIO4 and the corresponding caesium salts have been obtained through gravimetric measurements of the solubility in aqueous mixtures with methanol (MeOH) and propan-2-ol (PriOH) at 298.2 K. In addition, the solubility of Ph4P(pic) (pic = picrate anion) as well as K(pic) and KBPh4 and the corresponding caesium salts are reported in these mixtures at 298.2 K. Single-ion values of ΔtrsG° have been calculated using the tetraphenylphosphonium tetraphenylborate (TPTB) assumption. The semiempirical quantum-chemical AM1 method was used for calculations of interaction energy of BPh4- and Ph4P+ with a series of five solvent molecules and energy demands associated with a deformation of these ions. Trends observed for ΔtrsG° are discussed in terms of specific ion-solvent interactions and the structural effect of solvent mixtures.

The heat of dissolution of CsClO4 in mixtures of water and glycols

The enthalpies of solution of CsClO4 (m = 0.002-0.02) in aqueous solutions of mono-, di-, tri-, and tetraethylene glycols and polyethylene glycols 300,400, and 600 with glycol contents up to 30 wt % were determined at 298.15 K using an isotherm