13454-84-7

Basic information

• Product Name: CESIUM PERCHLORATE
• Synonyms: CESIUM PERCHLORATE;Caesium perchlorate;cesiumperchlorate,99+%;Perchloric acid, cesium salt;perchloricacid,cesiumsalt;Cesiumperchloratemetalsbasiswhitextl;CESIUM PERCHLORATE, 99.999%;CESIUM PERCHLORATE REAGENT
• CAS NO: 13454-84-7
• Molecular Formula: ClO₄*Cs
• Molecular Weight: 232.36
• EINECS: 236-643-0
• Product Categories: Cesium SaltsSynthetic Reagents;Metal and Ceramic Science;Oxidation;Perchlorates;Salts;Synthetic Reagents;metal perchlorate salt;Cesium Salts;Chemical Synthesis;Materials Science;Metal and Ceramic Science;Synthetic Reagents
• Mol File: 13454-84-7.mol
• Article Data: 5

Chemical Properties

• Melting Point: 250 °C (dec.)(lit.)
• Appearance: White/Crystals or Crystalline Powder
• Density: 3,327 g/cm3
• Water Solubility: Soluble in water.
• Sensitive: Hygroscopic
• Stability: hygroscopic
• CAS DataBase Reference: CESIUM PERCHLORATE(CAS DataBase Reference)
• NIST Chemistry Reference: CESIUM PERCHLORATE(13454-84-7)
• EPA Substance Registry System: CESIUM PERCHLORATE(13454-84-7)

Safety Data

• Hazard Codes: O
• Statements: 8
• Safety Statements: 17
• RIDADR: UN 1481 5.1/PG 2
• WGK Germany: 3
• TSCA: Yes
• HazardClass: 5.1
• PackingGroup: II
• Hazardous Substances Data: 13454-84-7(Hazardous Substances Data)

Usage

Chemical Properties

White crystals or crystalline powder

Uses

Different sources of media describe the Uses of 13454-84-7 differently. You can refer to the following data:
1. (Cesium perchlorate) Investigations of ionic conductivity in orientationally disordered phases1Used for:? ;Long-duration optical transmission of information with infofuses2? ;Modifier of polymer electrolyte/luminescent conjugated polymer mixed ionic-electronic conductors3? ;Studies involving pH-dependent mass and volume changes of polypyrrole / poly(styrene sulfonate)4? ;Cationic effects in polymer light-emitting electrochemical cells5Reactant for investigating metal salt effects on morphology of silica nanomaterials prepared by polymerization on hydrogels6
2. Cesium perchlorate is used for long-duration optical transmission of information with infofuses. It is a modifier of polymer electrolyte/luminescent conjugated polymer mixed ionic-electronic conductors. It has been used as a reactant for investigating metal salt effects on morphology of silica nanomaterials prepared by polymerization on hydrogels.
3. Investigations of ionic conductivity in orientationally disordered phasesUsed for:Long-duration optical transmission of information with infofusesModifier of polymer electrolyte/luminescent conjugated polymer mixed ionic-electronic conductorsStudies involving pH-dependent mass and volume changes of polypyrrole / poly(styrene sulfonate)Cationic effects in polymer light-emitting electrochemical cellsReactant for investigating metal salt effects on morphology of silica nanomaterials prepared by polymerization on hydrogels

Purification Methods

Crystallise it from water (4mL/g) between 100o and 0o.

InChI:InChI=1/ClHO4.Cs/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

Upstream product

• 7601-90-3 perchloric acid 
• 18437-47-3 cesium cupric chloride 
• 15690-63-8 cesium chloride 
• 7790-98-9 ammonium perchlorate 
• 13106-69-9 caesium methoxide 
• 534-17-8 caesium carbonate 
• 264619-02-5 caesium dimethylthiocarbamoylcyanoximate 

Downstream Products

• 15690-63-8 cesium chloride 
• 7783-54-2 nitrogen trifluoride 
• 16949-12-5 cesium hexafluoroantimonate 
• 10049-03-3 chlorine tetroxide fluoride 
• 13706-14-4 NF₄⁽¹⁺⁾*ClO₄^(1-)=NF₄ClO₄ 

Relevant articles and documents

Conductometric, Viscometric, and Spectroscopic Investigations on the Solvation Phenomena of Alkali-Metal Ions and Ion Pairs in 2-Methoxyethanol

Precise measurements on electrical conductances, relative viscosities, and laser-Raman spectra of solutions of some alkali-metal salts in 2-methoxyethanol (ME) have been reported.The conductance data were analyzed by the 1978 Fuoss conductance equation an

An improved method for product separation in metathetical reactions and its demonstration for the synthesis of anhydrous cesium salts

In conventional metathetical reactions, product separation is based on solubility product differences, and the resulting products are often impure and require purification by recrystallization. A new approach to product separation is described that relies on the formation of an unstable, volatile by-product, such as NH4+CH3O-. This method provides very pure and anhydrous products in high yield and was demonstrated successfully for the syntheses of anhydrous cesium salts.

Transfer Gibbs energies for ClO3-, BrO3-, IO3-, ClO4- and IO4- anions for water-methanol and water-propan-2-ol mixtures: Some quantum-chemical aspects of ionic solvation

The transfer Gibbs energies, ΔtrsG°, of KClO3, KBrO3, KIO3, KClO4, KIO4 and the corresponding caesium salts have been obtained through gravimetric measurements of the solubility in aqueous mixtures with methanol (MeOH) and propan-2-ol (PriOH) at 298.2 K. In addition, the solubility of Ph4P(pic) (pic = picrate anion) as well as K(pic) and KBPh4 and the corresponding caesium salts are reported in these mixtures at 298.2 K. Single-ion values of ΔtrsG° have been calculated using the tetraphenylphosphonium tetraphenylborate (TPTB) assumption. The semiempirical quantum-chemical AM1 method was used for calculations of interaction energy of BPh4- and Ph4P+ with a series of five solvent molecules and energy demands associated with a deformation of these ions. Trends observed for ΔtrsG° are discussed in terms of specific ion-solvent interactions and the structural effect of solvent mixtures.