1345470-53-2

Basic information

• Product Name: C₁₂H₁₀⁽²⁾HNOS
• CAS NO: 1345470-53-2
• Molecular Weight: 218.284
• Mol File: 1345470-53-2.mol

Chemical Properties

• CAS DataBase Reference: C₁₂H₁₀⁽²⁾HNOS(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₂H₁₀⁽²⁾HNOS(1345470-53-2)
• EPA Substance Registry System: C₁₂H₁₀⁽²⁾HNOS(1345470-53-2)

Safety Data

• Hazardous Substances Data: 1345470-53-2(Hazardous Substances Data)

Upstream product

• 1210812-23-9 2-(2-bromophenylsulfanyl)pyridine 

Relevant articles and documents

Palladium-catalyzed coupling of arene C-H bonds with methyl- and arylboron reagents assisted by the removable 2-pyridylsulfinyl group

The PdII-catalyzed direct coupling of arene C-H bonds with organoboron reagents assisted by the 2-pyridylsulfinyl group is reported. Methylboronic acid and arylboronic acid neopentyl esters proved to be efficient coupling partners, furnishing methylated arenes and biaryl products in moderate to good yields. The 2-pyridylsulfinyl group can be easily removed to provide the free biaryls. The essential role of the 2-pyridyl unit in stabilizing the cyclopalladation complex was demonstrated by X-ray diffraction analysis of the palladacycle intermediate.