134572-73-9Relevant academic research and scientific papers
SYNTHESIS OF NEW POLYMERIC RHODIUM CARBORANE COMPLEXES SERVING AS HOMOGENEOUS CATALYSTS FOR THE HYDROSILYLATION OF 1-HEXENE
Kats, G. A.,Komarova, L. G.,Rusanov, A. L.
, p. 855 - 857 (1991)
The coordination of Rh(PPh3)3Cl on a dicarbaundecaborate polyamide gives a new polymeric rhodium hydride complex with catalytic activity in the hydrosilylation of 1-hexene by triethylsilane.The rhodium derivative of 7,9-dicarbanido-undecaborate(11)-7,9-dicarboxyanilide was synthesized as a model of the monomeric unit.CoIII and NiIV bis(dicarbollyl) complexes also display catalytic activity in hydrosilylation reactions.
