SYNTHESIS OF NEW POLYMERIC RHODIUM CARBORANE COMPLEXES SERVING AS HOMOGENEOUS CATALYSTS FOR THE HYDROSILYLATION OF 1-HEXENE

DOI: 10.1007/BF00958592

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 855 - 857 (1991)

Update date:2022-07-29

Topics:

Authors:

Kats, G. A.

Komarova, L. G.

Rusanov, A. L.

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Article abstract of DOI:10.1007/BF00958592

The coordination of Rh(PPh3)3Cl on a dicarbaundecaborate polyamide gives a new polymeric rhodium hydride complex with catalytic activity in the hydrosilylation of 1-hexene by triethylsilane.The rhodium derivative of 7,9-dicarbanido-undecaborate(11)-7,9-dicarboxyanilide was synthesized as a model of the monomeric unit.Co^III and Ni^IV bis(dicarbollyl) complexes also display catalytic activity in hydrosilylation reactions.

Full text of DOI:10.1007/BF00958592

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