1345971-22-3Relevant academic research and scientific papers
Chiral allene-containing phosphines in asymmetric catalysis
Cai, Feng,Pu, Xiaotao,Qi, Xiangbing,Lynch, Vincent,Radha, Akella,Ready, Joseph M.
supporting information; experimental part, p. 18066 - 18069 (2012/01/04)
We demonstrate that allenes, chiral 1,2-dienes, appended with basic functionality can serve as ligands for transition metals. We describe an allene-containing bisphosphine that, when coordinated to Rh(I), promotes the asymmetric addition of arylboronic ac
