134600-25-2Relevant academic research and scientific papers
3-SUBSTITUTED 1-VINYL-1-METHYLCYCLOHEX-3-ENES - PRECURSORS OF TRICYCLIC DITERPENOIDS OF THE PIMARANE/ROSANE GROUP
Dragan, V. A.,Veselovskii, V. V.,Daeva, E. D.,Moiseenkov, A. M.
, p. 754 - 759 (1991)
The synthesis of 1-vinyl-1-methyl-3-chloromethylcyclohex-3-ene from 3-vinyl-3-methylcyclohexanone and the corresponding exomethylene derivative has been optimized and related allylsulfones prepared.By a standard combination of these compounds with the appropriate (cyclo)geranyl block synthones a series of regular functionalized diterpenoids has been prepared which are considered as likely precursors of the natural compounds indicated in the title.
