Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 754 - 759 (1991)
Update date:2022-08-02
Topics:
Dragan, V. A.
Veselovskii, V. V.
Daeva, E. D.
Moiseenkov, A. M.
The synthesis of 1-vinyl-1-methyl-3-chloromethylcyclohex-3-ene from 3-vinyl-3-methylcyclohexanone and the corresponding exomethylene derivative has been optimized and related allylsulfones prepared.By a standard combination of these compounds with the appropriate (cyclo)geranyl block synthones a series of regular functionalized diterpenoids has been prepared which are considered as likely precursors of the natural compounds indicated in the title.
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