3-SUBSTITUTED 1-VINYL-1-METHYLCYCLOHEX-3-ENES - PRECURSORS OF TRICYCLIC DITERPENOIDS OF THE PIMARANE/ROSANE GROUP

DOI: 10.1007/BF00958567

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 754 - 759 (1991)

Update date:2022-08-02

Topics:

Authors:

Dragan, V. A.

Veselovskii, V. V.

Daeva, E. D.

Moiseenkov, A. M.

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Article abstract of DOI:10.1007/BF00958567

The synthesis of 1-vinyl-1-methyl-3-chloromethylcyclohex-3-ene from 3-vinyl-3-methylcyclohexanone and the corresponding exomethylene derivative has been optimized and related allylsulfones prepared.By a standard combination of these compounds with the appropriate (cyclo)geranyl block synthones a series of regular functionalized diterpenoids has been prepared which are considered as likely precursors of the natural compounds indicated in the title.

Full text of DOI:10.1007/BF00958567

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