1346155-97-2Relevant academic research and scientific papers
PtI2-Catalyzed tandem 3,3-rearrangement/Nazarov reaction of arylpropargylic esters: Synthesis of indanone derivatives
Zheng, Huaiji,Xie, Xingang,Yang, Juan,Zhao, Changgui,Jing, Peng,Fang, Bowen,She, Xuegong
, p. 7755 - 7762 (2011)
An efficient PtI2-catalyzed tandem reaction of arylpropargylic esters, involving 3,3-rearrangement and Nazarov reaction, has been developed to produce 3-substituted and 3,3-disubstituted indanone derivatives. This approach provided a pathway to the synthesis of indanone skeletons in natural products.
Neighboring Carbonyl Group Assisted Hydration of Unsymmetrical Aryl Alkynes Overriding Regular Selectivity
Mendhekar, Kishor L.,Pradhan, Tapas R.,Mallampudi, N. Arjunreddy,Mohapatra, Debendra K.
, p. 5787 - 5797 (2019/08/21)
A mild and highly regioselective gold-catalyzed hydration of γ-acetoxy aryl alkynes leading to anti-Markovnikov products by the assistance of a neighboring carbonyl group is presented. The reaction procedure operates under room temperature conditions with
