134619-72-0Relevant articles and documents
Boron trihalide mediated haloallylation of aryl aldehydes and its application to the preparation of (E)-1,3-dienes
Quinn, Michael P.,Yao, Min-Liang,Yong, Li,Kabalka, George W.
experimental part, p. 3815 - 3820 (2012/01/05)
In the presence of boron trihalides, aryl aldehydes couple readily with allylmetals to afford haloallylated products. The reactions tolerate a variety of functional groups. Simple aqueous workup of haloallylation reactions, followed by treatment with 1,8-
Efficient and selective halogenation of allylic and benzylic alcohols under mild conditions
Bandgar, Babasaheb P.,Bettigeri, Sampada V.
, p. 1251 - 1255 (2007/10/03)
A simple, mild, and high yielding procedure for the halogenation of allylic and benzylic alcohols using a combination of SOCl2, benzotriazole, and potassium halides in DMF is described. The effectiveness of the protocol is manifested in its selectivity towards allylic and benzylic alcohols whereas other simple alcohols such as primary, secondary, and tertiary are found to be unreactive. Springer-Verlag 2004.