1346254-37-2Relevant articles and documents
Oxidant-controlled stereoselectivity in the Pd-catalyzed allylic oxidation of cis-vinylsilanes
Check, Christopher T.,Henderson, William H.,Wray, Brenda C.,Van Den Eynden, Matthew J.,Stambuli, James P.
, p. 18503 - 18505 (2011)
The allylic oxidation of cis-vinylsilanes is reported. The reaction requires a low catalyst loading of Pd(OAc)2 without the need for an external ligand. Interestingly, trans-vinylsilanes are unreactive, whereas allylic oxidations of cis-vinylsi