1346265-89-1Relevant academic research and scientific papers
Synthesis, Crystal Structure, and Magnetic Property of four Manganese(II) Complexes with Bulky Schiff bases Derived from Amantadine and Rimantadine
Jin,Feng,Bu,Wang,Tong,Zhang,Qi,Yang
, p. 230 - 237 (2019)
Abstract: The reactions of manganese(II) chloride tetrahydrate and four bulky Schiff base ligands derived from amantadine (or rimantadine) and salicylaldehyde (or 4-methoxysalicylaldehyde) generated four?novel?complexes, C34H42Clsub
Synthesis, characterization, and antibacterial activity of two zinc(II) complexes with Schiff bases derived from rimantadine
Jin,Xu,Yin,Wang,Zou,Liu,Ge,Chang,Jin
, p. 371 - 378 (2014/06/24)
The reactions of zinc(II) chloride and two Schiff base ligands derived from rimantadine and 5-chlorosalicylaldehyde/4-methoxysalicylaldehydes, generated two novel complexes [Zn(L1)2Cl2] (I) and [Zn(L2)2Cl2] (II), where L1 = 2-((1-(1-adamantan-1-yl)ethyl)-iminomethyl)-4-chlorophenol, L2 = 2-((1-(1-adamantan-1-yl)ethyl)iminomethyl)-5-methoxyphenol. The complexes were characterized by the means of IR, 1H NMR, elemental analysis, molar conductance and thermal analysis. A single-crystal X-ray diffraction analysis reveals that both complexes crystallize in orthorhombic system, space group Fdd2 for I and Pbcn for II. In two complexes crystals, each asymmetric unit consists of one zinc(II) ion, two corresponding Schiff base ligands and two chlorine atoms; the central zinc atom lies on a twofold rotation axis and is four-coordinate via two chlorine atoms and two oxygen atoms from the Schiff base ligands, forming a distorted tetrahedral geometry.
