134642-05-0Relevant academic research and scientific papers
2-Benzothiazolylchloromethyllithium: Synthesis of oxiranes
Florio,Troisi
, p. 7953 - 7956 (2007/10/02)
Deprotonation of 2-chloromethylbenzothiazole 1 with lithium diisopropylamide (LDA) in tetrahydrofuran (THF) at -78°C gives a red solution of 2-benzothiazolylchloromethyllithium 2, which couples with carbonyl compounds furnishing oxiranes 3.
STEREOSELECTIVE SYNTHESIS OF VINYLBENZOTHIAZOLES AND THEIR EPOXIDES
Florio, S.,Ingrosso, G.,Ronzini, L.,Epifani, E.
, p. 3365 - 3374 (2007/10/02)
Vinylbenzothiazoles 2 were stereoselectively prepared through isomerization of allylbenzothiazoles 1.Oxiranes 5 and 8 were synthesized from 2 and 1 via cyclization of the corresponding bromohydrins 3,4,6 and 7.
