134643-01-9Relevant articles and documents
Synthesis of C2 symmetric 2,2′-bipyridyl imidazolidinone and oxazaborolidine derivatives
Ward, Robert S.,Branciard, Denis,Dignan, Rosemary A.,Pritchard, Martyn C.
, p. 157 - 170 (2007/10/03)
4,4′-Bis(bromomethyl)-2,2′-bipyridine reacts with (4R, 5R)-1-propanoyl-4,5-diphenylimidazolidinone to form a C2 symmetric chiral bipyridine derivative. Similarly reaction of 4,4′-bis(bromomethyl)-2,2′-bipyridine with an amino alcohol prepared from L-tyrosine affords a C2 symmetric diaminodiol. Treatment of the latter product with either borane or trimethylboroxine forms oxazaborolidines that have been used as catalysts in the asymmetric reduction of acetophenone. High enantiomeric excesses are obtained.
New Chiral Auxiliary; 4,5-Diphenyl-1-methyl-2-imidazolidinone. Its Utility in Highly Enantioselective Aldol Reaction
Sankhavasi, Wongsiri,Yamamoto, Makoto,Kohmoto, Shigeo,Yamada, Kazutoshi
, p. 1425 - 1427 (2007/10/02)
The aldol reaction of the boron enolate bearing the titled chiral auxiliary proceeded with high face selectivity.