134736-82-6

Basic information

• Product Name: 2-Cyclohexene-1-acetic acid, 2,6,6-trimethyl-, ethyl ester, (R)-
• CAS NO: 134736-82-6
• Molecular Formula: C13H22O2
• Molecular Weight: 210.316
• Mol File: 134736-82-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexene-1-acetic acid, 2,6,6-trimethyl-, ethyl ester, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexene-1-acetic acid, 2,6,6-trimethyl-, ethyl ester, (R)-(134736-82-6)
• EPA Substance Registry System: 2-Cyclohexene-1-acetic acid, 2,6,6-trimethyl-, ethyl ester, (R)-(134736-82-6)

Safety Data

• Hazardous Substances Data: 134736-82-6(Hazardous Substances Data)

Upstream product

• 134780-17-9 (S)-2,4,4-trimethyl-2-cyclohexen-1-ol 
• 78-39-7 Triethyl orthoacetate 
• 134736-78-0 (+/-)-2,4,4-Trimethyl-2-cyclohexen-1-ol 
• 13395-71-6 2,4,4-trimethyl-2-cyclohexenone 

Downstream Products

• 24739-72-8 (R)-(2,6,6-trimethylcyclohex-2-enyl)acetic acid 
• 134736-83-7 2-<(R)-2,6,6-Trimethyl-2-cyclohexenyl>ethanol 
• 81800-41-1 (S)-dihydroactinidiolide 
• 1133-03-5 loliolide 
• 147730-45-8 (3S,3aR,7aS)-4,4,7a-trimethyl-3-(phenylselenyl)-3a,4,5,6,7,7a-hexahydrobenzofuran-2(3H)-one 
• 143658-49-5 2-(2,6,6-trimethyl-2-cyclohexenyl)ethanal 
• 143658-51-9 3-hydroxymethyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-penten-1-ol 
• 143728-95-4 3-formyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenal 
• 143658-50-8 methyl 3-methoxycarbonyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenoate 
• 39721-65-8 (R)-(+)-α-dihydroionone 
• 134736-85-9 2-<(R)-2,6,6-Trimethyl-2-cyclohexenyl>ethyl cyanide 
• 134736-84-8 2-<(R)-2,6,6-Trimethyl-2-cyclohexenyl>ethyl tosylate 

Relevant articles and documents

Carotenoids and Degraded Carotenoids, VIII. Synthesis of (+)-Dihydroactinidiolide, (+)- and (-)-Actinidiolide, (+)- and (-)-Loliolide as well as (+)- and (-)-Epiloliolide

Enantiomerically pure (S)-2,4,4-trimethyl-2-cyclohexen-1-ol (1) was efficiently converted into four degraded lactonic carotenoids: (S)-dihydroactinidiolide (5), (S)-actinidiolide (9), (6S,7aR)-loliolide (11) and (6S,7aS)-epiloliolide (12). (R)-Actinidioli

Preparative Bioorganic Chemistry, XV. - Preparation of Optically pure 2,4,4-Trimethyl-2-cyclohexen-1-ol, a New and Versatile Chiral Building Block in Terpene Synthesis

Enzymatic hydrolysis of (+/-)-2,4,4-trimethyl-2-cyclohexenyl acetate with pig liver esterase yielded (R)-(+)-2,4,4-trimethyl-2-cyclohexen-1-ol and unchanged (S)-(-)-acetate (S)-3.Enantiomerically pure (S)-2 was converted into (R)-dihydro