143658-50-8Relevant articles and documents
Synthesis of Mono- and Sesqui-terpenoids. XXI. Synthesis and Absolute Configuration of (E)-3-Formyl-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenal, a Sesquiterpenoid from a Marine Alga, Caulerpa ashmeadii
Mori, Kenji,Aki, Shinji
, p. 625 - 629 (2007/10/02)
A six-step synthesis of the enantiomers of (E)-3-formyl-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenal has been achieved, starting from the enantiomers of 2,4,4-trimethyl-2-cyclohexenol.By comparing the sign of the optical rotation of the naturally occurring